Single-molecule kinetic energy of condensed normal deuterium.

DEUTERIUM STUDIES IN THE DISPROPORTIONATION OF THIOXANTHYLIUM SALTS

Deuterium labelling is used to show that the disproportionation of thioxanthylium salts involve transfer of a hydride, (deuteride) ion from the9-positionof one molecule of the compound, as its hydro], to the 9 - position of another molecule in the cation form

Functional Unfolding of 1-Antitrypsin Probed by Hydrogen-Deuterium Exchange Coupled with Mass Spectrometry*□S

The native state of 1-antitrypsin ( 1AT), a member of the serine protease inhibitor (serpin) family, is considered a kinetically trapped folding intermediate that converts to a more stable form upon complex formation with a target protease. Although previous structural and mutational studies of 1AT revealed the structural basis of the native strain and the kinetic trap, the mechanism of how the...

Solubility and kinetic properties of deuterium in single crystal Pd

The pressure–composition (PC) behavior of deuterium in single crystal Pd has been measured over a temperature range extending from room temperature to 393 K. These data allow the determination of (i) relative partial molar enthalpy and entropy, without the contribution of the configuration entropy, for the dilute solid solution phase, (ii) enthalpy and entropy change characterizing the a→a9 pha...

Effect of Induced Dipole-Induced Dipole Potential and the Size of Colliding Particles on Ion-Quadrupolar Molecule Collision Rate Constants

Classical trajectory (Monte Carlo) calculation is used to calculate collision rate constants of ion-quadrupolar molecule interactions for the H¯+C2H2 system. The method presented here takes into account the effect of the induced dipole-induced dipole potential on ion-quadrupolar molecule collision rate constants. It is also assumed that the colliding particles have a d...

Carboxypeptidasey from Saccharomyces cerevisiae Conformational Difference Reflected in Kinetic Behaviour in Water and Deuterium Oxide